Structure and soft magnetic properties of nanocrystalline Fe73.5Nb2Ta1Si13.5B9Cu1 alloy ribbons
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https://doi.org/10.15625/0868-3166/22683Abstract
The crystal structure and soft magnetic properties of thermomagnetic annealed \(\text{Fe}_{73.5}\text{Nb}_{2}\text{Ta}_{1}\text{Si}_{13.5}\text{B}_{9}\text{Cu}_{1}\) alloy ribbons prepared by rapid cooling were investigated. X-ray diffraction results showed that the as-cast alloy strips had a completely amorphous structure, while the annealed samples formed \(\alpha\)-Fe (Si) nanocrystals with sizes ranging from 8 to 11 nm. Differential scanning calorimetry analysis of the as-cast samples indicated an exothermic crystallization peak at 515\(^{\circ}\)C of the first crystallization stage corresponding to the formation of the \(\alpha\)-Fe (Si) crystalline phase. The as-cast ribbon samples were annealed at 500\(^{\circ}\)C for 30, 40, and 50 minutes and in a saturation magnetic field of 10 Oe. The crystallinity of the alloy ribbons thermomagnetically annealed at 500\(^{\circ}\)C for 30 min was determined by DSC analysis to be 42%. The optimum annealing time at 500\(^{\circ}\)C in a saturated magnetic field for the amorphous alloy ribbons to achieve the best magnetic properties was 40 minutes. Under that condition, the \(\alpha\)- Fe (Si) phase crystallized completely, and the material exhibited excellent soft magnetic properties, with a saturation induction of \(\text{B}_{s} = 1.45\) T, coercivity \(\text{H}_{c} = 0.015\) Oe, and maximum permeability \(\mu_{\text{max}} = 551,500\).
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