A Study of the Optical Properties of Sm-doped ZnWO4 Synthesized by Hydrothermal Method

Abstract

The ZnWO₄:Sm³⁺ compounds were prepared by hydrothermal method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman scattering, absorption and photoluminescent (PL) techniques. This rare earth material presents high orange luminescence intensity under UV radiation. The excitation spectra of the compound presented broad bands arising from ligand-to-metal charge transfer (LMCT) (O®W and O®Sm³⁺) and narrow bands from 4f-intraconfigurational transitions. The emission spectra exhibited the ⁴G_5/2®⁶H_J (J = 5/2, 7/2, 9/2 and 11/2) transition (direct excitation), for the system doped with Sm³⁺, while a broad band assigned to the LMCT (O®W) is observed when the excitation is monitored on the O®W LMCT state.